Calibration of BVRI Photometry for the Wide Field Channel of the HST Advanced Camera for Surveys

We present new observations of two Galactic globular clusters, PAL4 and PAL14, using the Wide-Field Channel of the Advanced Camera for Surveys (ACS) on board the Hubble Space Telescope (HST), and reanalyze archival data from a third, NGC2419. We matched our photometry of hundreds of stars in these fields from the ACS images to existing, ground-based photometry of faint sequences which were calibrated on the standard BVRI system of Landolt. These stars are significantly fainter than those generally used for HST calibration purposes, and therefore are much better matched to supporting precision photometry of ACS science targets. We were able to derive more accurate photometric transformation coefficients for the commonly used ACS broad-band filters compared to those published by Sirianni, et al. (2005), owing to the use of a factor of several more calibration stars which span a greater range of color. We find that the inferred transformations from each cluster individually do not vary significantly from the average, except for a small offset of the photometric zeropoint in the F850LP filter. Our results suggest that the published prescriptions for the time-dependent correction of CCD charge-transfer efficiency appear to work very well over the ~3.5 yr interval that spans our observations of PAL4 and PAL14 and the archived images of NGC2419.Comment: 22 pages, 12 figures. Accepted for publication in PAS

LSST optical beam simulator

We describe a camera beam simulator for the LSST which is capable of illuminating a 60mm field at f/1.2 with realistic astronomical scenes, enabling studies of CCD astrometric and photometric performance. The goal is to fully simulate LSST observing, in order to characterize charge transport and other features in the thick fully depleted CCDs and to probe low level systematics under realistic conditions. The automated system simulates the centrally obscured LSST beam and sky scenes, including the spectral shape of the night sky. The doubly telecentric design uses a nearly unit magnification design consisting of a spherical mirror, three BK7 lenses, and one beam-splitter window. To achieve the relatively large field the beam-splitter window is used twice. The motivation for this LSST beam test facility was driven by the need to fully characterize a new generation of thick fully-depleted CCDs, and assess their suitability for the broad range of science which is planned for LSST. Due to the fast beam illumination and the thick silicon design [each pixel is 10 microns wide and over 100 microns deep] at long wavelengths there can be effects of photon transport and charge transport in the high purity silicon. The focal surface covers a field more than sufficient for a 40x40 mm LSST CCD. Delivered optical quality meets design goals, with 50% energy within a 5 micron circle. The tests of CCD performance are briefly described.Comment: 9 pages, 9 figure

Identification of Cool White Dwarfs in the NOAO Deep Wide-Field Survey

We report our search for the cool white dwarfs belonging to the Galactic disk by extending the NOAO Deep Wide-Field Survey. Narrow-band DDO51 photometry of the Deep Wide-Field Survey's northern field was obtained using the 4m-Mayall Telescope and the MOSAIC imager to separate cool white dwarfs from other stellar types of similar T_eff. Follow-up spectroscopy of four white dwarf candidates from our photometric search resulted in the discovery of two new cool white dwarfs as companions to M dwarfs.Comment: 2 pages, 2 figures, to appear in proceedings of the 13th European Workshop on White Dwarf

Photometric Identification of Cool White Dwarfs

We investigate the use of a narrow-band DDO51 filter for photometric identification of cool white dwarfs. We report photometric observations of 30 known cool white dwarfs with temperatures ranging from 10,000 K down to very cool temperatures (<3500 K). Follow-up spectroscopic observations of a sample of objects selected using this filter and our photometric observations show that DDO51 filter photometry can help select cool white dwarf candidates for follow-up multi--object spectroscopy by rejecting 65% of main sequence stars with the same broad--band colors as the cool white dwarfs. This technique is not selective enough to efficiently feed single--object spectrographs. We present the white dwarf cooling sequence using this filter. Our observations show that very cool white dwarfs form a sequence in the r-DDO vs. r-z color--color diagram and demonstrate that significant improvements are needed in white dwarf model atmospheres.Comment: Accepted for publication in A

Photometry and spectroscopy of faint candidate spectrophotometric standard DA white dwarfs

We present precise photometry and spectroscopy for 23 candidate spectrophotometric standard white dwarfs. The selected stars are distributed in the Northern hemisphere and around the celestial equators and are all fainter than r ~ 16.5 mag. This network of stars, when established as standards, together with the three Hubble Space Telescope primary CALSPEC white dwarfs, will provide a set of spectrophotometric standards to directly calibrate data products to better than 1%. These new faint standard white dwarfs will have enough signal-to-noise ratio in future deep photometric surveys and facilities to be measured accurately while still avoiding saturation in such surveys. They will also fall within the dynamic range of large telescopes and their instruments for the foreseeable future. This paper discusses the provenance of the observational data for our candidate standard stars. The comparison with models, reconciliation with reddening, and the consequent derivation of the full spectral energy density distributions for each of them is reserved for a subsequent paper.Comment: 31 pages, 17 figures, 10 tables, ApJ in press (accepted on December 23rd, 2018

Panoramic Views of the Cygnus Loop

We present a complete atlas of the Cygnus Loop supernova remnant in the light of [O III] (5007), H alpha, and [S II] (6717, 6731). Despite its shell-like appearance, the Cygnus Loop is not a current example of a Sedov-Taylor blast wave. Rather, the optical emission traces interactions of the supernova blast wave with clumps of gas. The surrounding interstellar medium forms the walls of a cavity through which the blast wave now propagates, including a nearly complete shell in which non-radiative filaments are detected. The Cygnus Loop blast wave is not breaking out of a dense cloud, but is instead running into confining walls. The interstellar medium dominates not only the appearance of the Cygnus Loop but also the continued evolution of the blast wave. If this is a typical example of a supernova remnant, then global models of the interstellar medium must account for such significant blast wave deceleration.Comment: 28 pages AAS Latex, 28 black+white figures, 6 color figures. To be published in The Astrophysical Journal Supplement Serie

Recyclable NHC catalyst for the development of a generalized approach to continuous Buchwald-Hartwig reaction and work-up

A generalized approach to the optimization and implementation of Buchwald-Hartwig reactions in flow is reported, through the combination of three key factors: a highly active palladium catalyst; a universal approach for continuous work-up and purification, and a methodology for catalyst recycling and reuse. The palladium N-heterocyclic carbene (NHC) pre-catalyst [Pd(IPr*)(cin)Cl] 4 (IPr* = 1,3-bis(2,6-bis(diphenylmethyl)-4-methylphenyl)imidazol-2-ylidene; cin = η3-cinnamyl) is an excellent choice for continuous Buchwald-Hartwig reactions, due to its inherent high activity and stability. In preparation for running this reaction in flow (published concurrently), a detailed study has been carried out into its water stability, ultimately allowing the recycling of the catalyst in the organic phase up to 3 times in batch mode. A “right-first-time” work-up methodology has also been developed, resulting in a universal protocol that allows the selective extraction of the Buchwald-Hartwig product into the aqueous stream as a salt, while retaining the aryl bromide starting material in the organic stream with the catalyst, thus negating the requirement for further purification. It is therefore envisaged that this approach will particularly amenable to exploitation in the Pharmaceutical industry. An optimized, scalable synthesis of [Pd(IPr*)(cin)Cl] is also reported on multi-hundred gram scale

Sub-percent Photometry: Faint DA White Dwarf Spectophotometric Standards for Astrophysical Observatories

We have established a network of 19 faint (16.5 mag $< V <$19 mag) northern and equatorial DA white dwarfs as spectrophotometric standards for present and future wide-field observatories. Our analysis infers SED models for the stars that are tied to the three CALSPEC primary standards. Our SED models are consistent with panchromatic Hubble Space Telescope ($HST$) photometry to better than 1%. The excellent agreement between observations and models validates the use of non-local-thermodynamic-equilibrium (NLTE) DA white dwarf atmospheres extinguished by interstellar dust as accurate spectrophotometric references. Our standards are accessible from both hemispheres and suitable for ground and space-based observatories covering the ultraviolet to the near infrared. The high-precision of these faint sources make our network of standards ideally suited for any experiment that has very stringent requirements on flux calibration, such as studies of dark energy using the Large Synoptic Survey Telescope (LSST) and the Wide-Field Infrared Survey Telescope ($WFIRST$).Comment: 46 pages, 23 figures, 8 tables, accepted for publication in ApJ